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Question

Question: In the reaction: \[3Br_{2} + 6CO_{3}^{2 -} + 3H_{2}O \rightarrow 5Br^{-} + BrO_{3}^{-} + 6HCO_{3}^{...

In the reaction:

3Br2+6CO32+3H2O5Br+BrO3+6HCO33Br_{2} + 6CO_{3}^{2 -} + 3H_{2}O \rightarrow 5Br^{-} + BrO_{3}^{-} + 6HCO_{3}^{-}

A

Bromine is reduced and carbonate ion is oxidised.

B

Bromine undergoes disproportionation.

C

Bromine is reduced and water is oxidised.

D

Only water is oxidised to carbonic acid.

Answer

Bromine undergoes disproportionation.

Explanation

Solution

3Br2+6CO32+3H2O5Br+BrO3+6HCO33Br_{2} + 6CO_{3}^{2 -} + 3H_{2}O \rightarrow 5Br^{-} + BrO_{3}^{-} + 6HCO_{3}^{-}

Here Br2Br_{2}is both reduced and oxidised.

Br2(0)Br(1)Br_{2}(0) \rightarrow Br^{-}( - 1) (reduction)

Br2(0)BrO3(+5)Br_{2}(0) \rightarrow BrO_{3}^{-}( + 5) (oxidation)