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Question

Chemistry Question on Redox reactions

In the reaction 2Na2S2O3+I2>Na2S4O6+NaI {2 Na_2S_2O_3 + I_2 -> Na_2 S_4 O_6 + NaI} the oxidation number of sulphur is

A

decreased

B

increased

C

unchanged

D

none of these

Answer

increased

Explanation

Solution

Na2S2O3=+2+2x6=0 {Na_2S_2O_3 = + 2 + 2x-6 = 0 } or 2x=42x = 4 or x=+2x = + 2. Na2S4O6=+2+4x12=0 {Na_2S_4O_6 = + 2 + 4x - 12 = 0} or 4x=104 x = 10 or x=104=2.5x = \frac{10}{4}= 2.5 Here, the O.N. of S is increased.