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Question

Chemistry Question on Amines

In the given set of reactions, 2-Bromopropane >[AgCN][alc./heat]X>[LiAlH4]Y{ ->[{\text{AgCN}}][{\text{alc./heat}}] X ->[LiAlH_4] Y} the IUPACIUPAC name of product Y'Y' is

A

NN-methylpropanamine

B

NN-isopropylmethanamine

C

butan-22-amine

D

NN-Methylpropan-2-amine

Answer

NN-Methylpropan-2-amine

Explanation

Solution

AgCNAgCN is mainly covalent in nature and nitrogen is free to donate electron pair forming isocyanide as the main product.

Isonitriles on reduction with lithium aluminium hydride (LiAlH4)( LiAlH _{4} ) produce secondary amines