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Question

Chemistry Question on Alcohols, Phenols and Ethers

In the following sequence of reactions, CH3BrKCNAH3O+BLiAlH4CCH _{3}- Br \stackrel{ KCN }{\longrightarrow} A \stackrel{ H _{3} O ^{+}}{\longrightarrow} B \stackrel{ LiAlH _{4}}{\longrightarrow} C, the end product C is

A

Acetone

B

Methane

C

Acetaldehyde

D

Ethyl alcohol

Answer

Ethyl alcohol

Explanation

Solution

The correct answer is D:Ethyl alcohol
CH3BrKCNCH3CNH3O+CH3COOHLiAlH4CH3CH2OHCH _{3}- Br \stackrel{ KCN }{\longrightarrow} CH _{3}- CN \stackrel{ H _{3} O ^{+}}{\longrightarrow} CH _{3} COOH \stackrel{ LiAlH _{4}}{\longrightarrow} CH _{3} CH _{2} OH
Methyl bromide undergoes a reaction with KCN KCN to produce acetonitrile, where the bromine atom is substituted with a cyanide group. The subsequent hydrolysis of the cyanide group results in the formation of a carboxylic group. Finally, the reduction of the carboxylic group leads to the formation of a hydroxyl group.