Question
Question: In the following reaction sequence in aqueous solution, the species X, Y and Z respectively, are: ...
In the following reaction sequence in aqueous solution, the species X, Y and Z respectively, are:
s2o32−Ag+XAg+YwithtimeZ
(Clear solution) (white precipitate) (black precipitate)
A. [Ag(S2O3)2]3−,Ag2S2O3,Ag2S
B. [Ag(S2O3)2]5−,Ag2S2O3,Ag2S
C. [Ag(SO3)2]3−,Ag2S2O3,Ag
D. [Ag(SO3)3]3−,Ag2SO4,Ag
Solution
We know that thiosulphate ions when added to silver produce a clear solution. Also, we know that silver with thiosulphate produces a white precipitate of silver thiosulphate, Ag2S2O3
Complete step by step solution:
We are aware of the reaction that silver with thiosulphate S2O32− can give a white precipitate of silver thiosulphate ,Ag2S2O3. And thus, the white precipitate can possibly dissolve in an excess of thiosulphate.
1. While performing the experiments, we notice that the silver Ag+ is added drop by drop to the thiosulphate solution. When we add drop by drop silver Ag+ we get a complex. Since the coordination number of silver is 2, so we have two thiosulphate ions, and the charge of silver and thiosulphate add up to this complex to charge -3, thus the complex formed will be [Ag(S2O3)2]3−. So, we got the X which is a clear solution of the formula [Ag(S2O3)2]3−.
2. Now we have an excess of this complex and to this, we are adding the excess Ag+, since the thiosulphate is limited, we get Ag2S2O3. This will be a white precipitate. So, Y which is a white precipitate is the Ag2S2O3.
3. So, after some time, the Ag2S2O3 formed will react with water H2O, to give Ag2S
Ag2S2O3H2OAg2S(s)+H2SO4
This is a disproportionation reaction of thiosulphate to produce Ag2S and H2SO4, since the Ag2+ is water soluble it forms Ag2S. Therefore this is the black precipitate Z.
Therefore the correct option is A
Note:
The compound Ag2S2O3 will change its colour three or four times with time to finally give a black precipitate. Silver thiosulphate when it is fresh it is white. Slowly within seconds we can see there is a change to yellow, it then changes to orange, then brown and finally black