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Question: In the equation Rate \({\text{ = }}\,\,{\text{ZAB}}\,{\text{.}}\,{{\text{e}}^{\dfrac{{{\text{ - Ea}}...

In the equation Rate  = ZAB.e - EaRT{\text{ = }}\,\,{\text{ZAB}}\,{\text{.}}\,{{\text{e}}^{\dfrac{{{\text{ - Ea}}}}{{{\text{RT}}}}}}, what does ZAB{\text{ZAB}} mean?

Explanation

Solution

According to the collision theory, only a certain number of collisions between suitable reactant particles result in a perceptible or noticeable change; these successful changes are referred to as successful collisions.

Complete answer:
Max Trautz and William Lewis both suggested collision theory in the years 19161916 and 19181918, respectively.
At the moment of impact, efficient collisions must have enough energy, also known as activation energy, to sever pre-existing bonds and form all new bonds. As a consequence, the reaction's products are formed.
More collisions and hence more active collisions result from increasing the concentration of the reactant. The average kinetic energy of the molecules in a solution increases as the temperature rises, raising the number of collisions with sufficient energy.
The rate of a chemical reaction can be expressed as ZAB.e - EaRT{\text{ZAB}}\,{\text{.}}\,{{\text{e}}^{\dfrac{{{\text{ - Ea}}}}{{{\text{RT}}}}}} using collision theory.
The collision frequency of the reactants A{\text{A}} and B{\text{B}} is represented by ZAB{\text{ZAB}}.
When two reactant molecules collide successfully, each with the least amount of energy and the correct orientation, a reaction occurs.
In the reaction A + BAB{\text{A}}\,{\text{ + }}\,{\text{B}}\, \to \,{\text{AB}}. The reaction rate is proportional to the number of active collisions. As a result, the reaction rate can be expressed as ZAB.e - EaRT{\text{ZAB}}\,{\text{.}}\,{{\text{e}}^{\dfrac{{{\text{ - Ea}}}}{{{\text{RT}}}}}}
Ea(J/mol){\text{Ea}}\,\left( {{\text{J/mol}}} \right) is the activation energy.

Note:
When a catalyst is present in the collision between the reactant molecules, the chemical change requires less energy, and therefore more collisions have sufficient energy for reaction to occur. As a result, the reaction rate accelerates. Chemical kinetics and collision theory are inextricably linked.