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Question

Chemistry Question on GROUP 1 ELEMENTS

In the electrolysis of which solution, OHOH^- ions are discharged in preference to ClCl^- ions ?

A

dilute NaClNaCl

B

very dilute NaClNaCl

C

fused NaClNaCl

D

solid NaClNaCl

Answer

very dilute NaClNaCl

Explanation

Solution

In case of very dilute solution of NaClNaCl, electrolysis brings in the following changes Anode : 2OHH2O+12O2+2e2OH^{-} \to H_{2}O+\frac{1}{2}O_{2}+2e^{-} Cathode : 2H++2eH22H^{+}+2e^{-} \to H_{2}