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Question

Question: In the electrolysis of aqueous CuBr₂ using Pt electrodes...

In the electrolysis of aqueous CuBr₂ using Pt electrodes

A

Br₂ gas is evolved at the anode

B

Cu(s) is deposited at the cathode

C

Br₂ gas is evolved at anode and H₂ gas at cathode

D

H₂ gas is evolved at anode.

Answer

Br₂ gas is evolved at the anode, Cu(s) is deposited at the cathode

Explanation

Solution

Electrolysis of aqueous CuBr₂ involves the reduction of Cu²⁺ to Cu(s) at the cathode due to its higher reduction potential compared to water. At the anode, Br⁻ is oxidized to Br₂(l) due to its lower reduction potential compared to water. Therefore, Cu(s) is deposited at the cathode and Br₂ is evolved at the anode. Both statements (A) and (B) accurately describe these processes.