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Question

Chemistry Question on Redox reactions

In the disproportionation reaction 3HClO3>HClO4+Cl2+2O2+H2O {3 \, HClO_3 -> HClO_4 + Cl_2 + 2 O_2 + H_2O} the equivalent mass of the oxidising agent is (molar mass of HClO3=84.45 {HClO_3 = 84.45})

A

16.89

B

32.22

C

84.45

D

28.15

Answer

16.89

Explanation

Solution

ClO3>Cl20 {ClO^{-}_3 -> Cl_2^{0}}; In ClO3=x6=1 {ClO^{-}_3 = x - 6 = - 1} or x=+5x = + 5 E mass of ClO3{ClO^{-}_3} =Mol.massofClO3Oxidationnumberchange=84.455=16.89 = {\frac{Mol. \, mass \, of \, ClO^{-}_3}{Oxidation \, number \, change} = \frac{84.45}{5} = 16.89}