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Question

Chemistry Question on coordination compounds

In the complex ion [Cu(CN)4]3\left[Cu\left(CN\right)_{4}\right]^{3-} the hybridization state, oxidation state and number of unpaired electrons of copper are respectively

A

dsp2,+1,1dsp^{2},+1,1

B

sp3,+1,Zerosp^{3},+1,Zero

C

sp3,+2,1sp^{3},+2,1

D

dsp3,+2,Zerodsp^{3}, +2, Zero

Answer

sp3,+1,Zerosp^{3},+1,Zero

Explanation

Solution

[Cu+1(CN)44]3\left[Cu^{+1}\left(CN\right)^{-4}_{4}\right]^{-3}
cu+cu^{+} ground state=CN ()\left(-\right)is strong field ligand, Δ\Delta is high
Hybridisation =sp3;=sp^{3};oxidation state of Cu = +1
Number of unpaired electron = 0