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Question

Physical Chemistry Question on Electrochemistry

In the cell reaction
P+(π‘Žπ‘ž)+Q(𝑠)β†’P(𝑠)+Q+(π‘Žπ‘ž)
the EMF of the cell, 𝐸𝑐𝑒𝑙𝑙 is zero. The standard EMF of the cell, πΈπ‘œπ‘π‘’π‘™π‘™ is
[Given:
Activities of all solids are unity.
Activity of P+(π‘Žπ‘ž) is 2 M. Activity of Q+(π‘Žπ‘ž) is 1 M.
𝑅 = universal gas constant; 𝑇 = temperature; 𝐹 = Faraday constant]

A

RTF\frac{RT}{F}

B

RT2F\frac{RT}{2F}

C

βˆ’RTFIn(2)-\frac{RT}{F}In(2)

D

RTFIn(2)\frac{RT}{F}In(2)

Answer

βˆ’RTFIn(2)-\frac{RT}{F}In(2)

Explanation

Solution

The correct option is (C): βˆ’RTFIn(2)-\frac{RT}{F}In(2)