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Question

Chemistry Question on d block elements

In neutral or faintly alkaline medium, thiosulphate is quantitatively oxidized by KMnO4KMnO_4 to

A

SO32SO_3^{2-}

B

SO42SO^{2-}_4

C

SO2SO_2

D

SO52SO_5^{2-}

Answer

SO42SO^{2-}_4

Explanation

Solution

In neutral or alkaline mediunt, thiosuphate is quantitavely oxidized by KMnO4KMnO _{4} to SO42SO _{4}^{2-}
8MnO4+3S2O32+H2O8MnO2+6SO42+2OH8 MnO _{4}^{-}+3 S _{2} O _{3}^{2-}+ H _{2} O \to 8 MnO _{2}+6 SO _{4}^{2-}+2 OH ^{-}