Question
Chemistry Question on Hydrocarbons
In Friedel-Craft's synthesis of toluene, the reactants in addition to anhydrous AlCl3 are
A
C6H5Cl+CH4
B
C6H5CI+CH3Cl
C
C6H6+CH4
D
C6H6+CH3Cl
Answer
C6H6+CH3Cl
Explanation
Solution
Friedel-Craft's alkylation of benzene (Ar-H) .Mechanism of this reaction is represented as follows:
Step I
CH3Cl+AlCl3⟶ElectrophileCH3++AlCl4−
Thus, C6H6 and CH3Cl are required in addition to
AlCl3.