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Question

Chemistry Question on Hydrocarbons

In Friedel-Craft's synthesis of toluene, the reactants in addition to anhydrous AlCl3AlCl_3 are

A

C6H5Cl+CH4C_6 H_5 Cl + CH_4

B

C6H5CI+CH3ClC_6 H_5 CI + CH_3 Cl

C

C6H6+CH4C_6 H_6 + CH_4

D

C6H6+CH3ClC_6 H_6 + CH_3 Cl

Answer

C6H6+CH3ClC_6 H_6 + CH_3 Cl

Explanation

Solution

Friedel-Craft's alkylation of benzene (Ar-H) .Mechanism of this reaction is represented as follows:
Step I
CH3Cl+AlCl3ElectrophileCH3++AlCl4CH_3 Cl+AlCl_3 \longrightarrow \, \, \, \, ^{\, \, \, \, \, \, \, \, ^{+}_{CH_3}}_{Electrophile} \, \, \, \, +AlCl^-_4
Thus, C6H6C_6 H_6 and CH3ClCH_3 Cl are required in addition to
AlCl3AlCl_3.