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Question

Chemistry Question on Organic Chemistry- Some Basic Principles and Techniques

In Dumas method for the estimation of N2N _2, the sample is heated with copper oxide and the gas evolved is passed over :

A

Copper gauze

B

PdPd

C

NiNi

D

Copper oxide

Answer

Copper gauze

Explanation

Solution

Duma's method.
The nitrogen containing organic compound, when heated with CuO in a atmosphere of CO2​, yields free N2​ in addition to CO2​ and H2​O.
Cx​Hy​Nz​+(2x+2y​)CuO→
xCO2​+2y​H2​O+2z​N2​+(2x+2y​)Cu
Traces of nitrogen oxides formed, if any, are reduced to nitrogen by passing the gaseous mixture over heated copper gauze.
So, the correct option is (A) : Copper gauze