Question
Chemistry Question on Organic Chemistry- Some Basic Principles and Techniques
In Dumas method for the estimation of N2, the sample is heated with copper oxide and the gas evolved is passed over :
A
Copper gauze
B
Pd
C
Ni
D
Copper oxide
Answer
Copper gauze
Explanation
Solution
Duma's method.
The nitrogen containing organic compound, when heated with CuO in a atmosphere of CO2, yields free N2 in addition to CO2 and H2O.
CxHyNz+(2x+2y)CuO→
xCO2+2yH2O+2zN2+(2x+2y)Cu
Traces of nitrogen oxides formed, if any, are reduced to nitrogen by passing the gaseous mixture over heated copper gauze.
So, the correct option is (A) : Copper gauze