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Question

Chemistry Question on Organic Chemistry- Some Basic Principles and Techniques

In Carius method of estimation of halogens 250mg250\, mg of an organic compound gave 141mg141\, mg of AgBrAgBr. The percentage of bromine in the compound is (atomic mass Ag=108,Br=80Ag\, =\, 108, Br \,= \,80)

A

24

B

36

C

48

D

60

Answer

24

Explanation

Solution

moles of Br=1×Br =1 \times moles of AgBrAgBr
=1×141×103188=1 \times \frac{141 \times 10^{-3}}{188}

mass of Br=141×103188×80Br =\frac{141 \times 10^{-3}}{188} \times 80
%\therefore \% of Br=141×103188×80250×103×100 Br =\frac{141 \times 10^{-3}}{188} \times \frac{80}{250 \times 10^{-3}} \times 100
=24%=24 \%