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Question: In \(BX_{3},B - X\) distance is shorter than what is expected theoretically because (X = F, Cl, Br, ...

In BX3,BXBX_{3},B - X distance is shorter than what is expected theoretically because (X = F, Cl, Br, I)

A

sp3sp^{3} hybridization of B is responsible for shorter B – X distance.

B

B – X has a double bond character due to back – bonding

C

Dimerisation takes place in BX3BX_{3} which is responsible for shorter B – X distance.

D

Due to large size of X, B – X distance decreases.

Answer

B – X has a double bond character due to back – bonding

Explanation

Solution

: Due to back – bonding, B – X in BX3BX_{3} has double bond character which because of resonance results in shorter B – X distance.