Question
Chemistry Question on Haloalkanes and Haloarenes
In an SN1 reaction on chiral centres, there is :
A
100% retention
B
100% inversion
C
100% racemization
D
inversion more than retention leading to partial recemization
Answer
inversion more than retention leading to partial recemization
Explanation
Solution
SN1 reaction gives racemic mixture with slight predominance of that isomer which corresponds to inversion because SN1 also depends upon the degree of 'shielding' of the front side of the reacting carbon.