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Question

Chemistry Question on Thermodynamics

In an isobaric process, when temperature changes from T1T_1 to T2T_2, ΔS\Delta S is equal to

A

2.303CPlog(T2/T1)2.303\, C_{P} \log \left(T_{2} / T_{1}\right)

B

2.303CPlog(T2/T1)2.303 \,C_{P} \log \left(T_{2} / T_{1}\right)

C

Cpln(T1/T2)C_{p} \ln \left(T_{1} / T_{2}\right)

D

CVln(T2/T1)C_{V} \ln \left(T_{2} / T_{1}\right)

Answer

2.303CPlog(T2/T1)2.303\, C_{P} \log \left(T_{2} / T_{1}\right)

Explanation

Solution

The entropy change for a process, when TT and PP are the variables is given by ΔS=CPInT2T1RInP2P1\Delta S=C_{P} \,In\, \frac{T_{2}}{T_{1}}-R\, In\, \frac{P_{2}}{P_{1}} For an isobaric process P1=P2P_1 = P_2. Hence the above equation reduces to CPInT2T1=ΔS.C_{P}In \frac{T_{2}}{T_{1}}=\Delta S. or ΔS=2.303CPlogT2T1.\Delta S=2.303C_{P}\, log \frac{T_{2}}{T_{1}}.