Solveeit Logo

Question

Question: In an isobaric process, \(\Delta Q=\dfrac{K\gamma }{\gamma -1}\) where \(\gamma =\dfrac{{{C}_{p}}}{{...

In an isobaric process, ΔQ=Kγγ1\Delta Q=\dfrac{K\gamma }{\gamma -1} where γ=CpCv\gamma =\dfrac{{{C}_{p}}}{{{C}_{v}}}. What is K?
A. Pressure\text{A}\text{. Pressure}
B. Volume\text{B}\text{. Volume}
C. ΔU\text{C}\text{. }\Delta U
D. ΔW\text{D}\text{. }\Delta W

Explanation

Solution

In thermodynamics, isobaric process is a process in which pressure of the system remains constant throughout the process.
First law of thermodynamics will be helpful in solving this problem. According to this law, when heat is added to a system it is only used to change its internal energy and do some work.

Formula used: For an isobaric process, Heat ΔQ=nCpΔT\Delta Q=n{{C}_{p}}\Delta T and work done on the system ΔW=nRΔT\Delta W=nR\Delta T

Complete step by step answer:
First law of thermodynamics states, “the internal energy of a system has to be equal to the work that is being done on the system, plus or minus the heat that flows in or out of the system respectively and any other work that is done on the system.”
If ΔQ\Delta Q is the heat added to system, ΔU\Delta U be the change in its internal energy and, ΔW\Delta W is the work done on the system then according to first law of thermodynamics
ΔQ=ΔU+ΔW\Delta Q=\Delta U+\Delta W
This law is based on conservation of energy, for heat being a form of energy can neither be created nor destroyed.
A thermodynamic process is the process when the values of thermodynamic variables associated with a system change from one equilibrium to another.
In an isobaric process, pressure does not change throughout the process.
For an isobaric process, ΔU=nCvΔT\Delta U=n{{C}_{v}}\Delta Tand ΔW=nRΔT\Delta W=nR\Delta T
Therefore according to first law,
ΔQ=nCvΔT+nRΔT\Delta Q=n{{C}_{v}}\Delta T+nR\Delta T
Since Cp=Cv+R{{C}_{p}}={{C}_{v}}+R
ΔQ=nCpΔT\Delta Q=n{{C}_{p}}\Delta T …..(1)
Where Cp{{C}_{p}}and Cv{{C}_{v}} are molar heat capacity at constant pressure and volume respectively. RR is the universal gas constant and nnis the number of moles of gas.
According to the question, ΔQ=Kγγ1\Delta Q=\dfrac{K\gamma }{\gamma -1}
Let us simplify this equation by substituting γ=CpCv\gamma =\dfrac{{{C}_{p}}}{{{C}_{v}}} and the equation it with equation (1).
ΔQ=KCpCvCpCv1=KCpCpCv\Delta Q=\dfrac{K\dfrac{{{C}_{p}}}{{{C}_{v}}}}{\dfrac{{{C}_{p}}}{{{C}_{v}}}-1}=\dfrac{K{{C}_{p}}}{{{C}_{p}}-{{C}_{v}}}
ΔQ=KCpR\Delta Q=\dfrac{K{{C}_{p}}}{R} (because Cp=Cv+R{{C}_{p}}={{C}_{v}}+R)
ΔQ=KCpR=nCpΔT\Rightarrow \Delta Q=\dfrac{K{{C}_{p}}}{R}=n{{C}_{p}}\Delta T
On solving, we get
K=nRΔT=ΔWK=nR\Delta T=\Delta W

So, the correct answer is “Option D”.

Note: Heat is defined as energy in transit as a result of temperature difference.
Work done, in the thermodynamics process, is defined as a product of pressure on the system and change in its volume. In an isobaric process, for an ideal gas, if P and VV are pressure and the volume of the system respectively, then
ΔW=PΔV=nRΔT\Delta W=P\Delta V=nR\Delta T