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Question: In an atom, an electron is moving with a speed of 600 m/s with an accuracy of 0.005%, certainty with...

In an atom, an electron is moving with a speed of 600 m/s with an accuracy of 0.005%, certainty with which the position of the electron can be located is: (h=h = 6.6×1034kgm2s16.6\times {{10}^{-34}}kg{{m}^{2}}{{s}^{-1}}, mass of electron em=9.1×1031Kg{{e}_{m}}=9.1\times {{10}^{-31}}Kg).
(A) 1.52×104m1.52\times {{10}^{-4}}m
(B) 5.01×103m5.01\times {{10}^{-3}}m
(C) 1.92×103m1.92\times {{10}^{-3}}m
(D) 3.84×103m3.84\times {{10}^{-3}}m

Explanation

Solution

The location of electrons in a nucleus is determined by the Heisenberg’s Uncertainty Principle. The accuracy calculations for velocity and position is done by the relation stated by the same.

Complete step by step solution:
Let us know what do we mean by Heisenberg’s Uncertainty Principle and then concentrate on the given illustration,
Heisenberg’s Uncertainty Principle-
It states that it is not possible to measure both position and momentum (or velocity) of a microscopic particle simultaneously with specific accuracy.
Mathematically, the above statement will be expressed as,
Δx×Δph4π\Delta x\times \Delta p\ge \dfrac{h}{4\pi }
where,
Δx\Delta x= uncertainty in position
Δp\Delta p= uncertainty in momentum
The sign \ge means that the product of Δx\Delta x and Δp\Delta p can be either greater than or equal to h4π\dfrac{h}{4\pi }. It can be never less than h4π\dfrac{h}{4\pi } .
Fact-
If the position of the particle is measured accurately, then there will be more error in the measurement of momentum and vice versa is true.
Now,
As momentum is a product of mass and velocity. Therefore, we can say,
Δp=mΔv\Delta p=m\Delta v
mass is constant.
Thus,
Δx×Δvh4πm\Delta x\times \Delta v\ge \dfrac{h}{4\pi m}
It means that the position and velocity cannot be calculated simultaneously with accuracy.
Illustration-
Given that,
h=h = 6.6×1034kgm2s16.6\times {{10}^{-34}}kg{{m}^{2}}{{s}^{-1}}
em=9.1×1031Kg{{e}_{m}}=9.1\times {{10}^{-31}}Kg
As we know,
Δx×Δvh4πm\Delta x\times \Delta v\ge \dfrac{h}{4\pi m}
Thus,
Δv=600×0.005100=0.03m/sec\Delta v=600\times \dfrac{0.005}{100}=0.03m/\sec
as accuracy is given as 0.005%.
Now,
Δxh4mΔvπ Δx6.6×10344×9.1×1031×0.03×3.14 Δx1.9248×103m \begin{aligned} & \Delta x\ge \dfrac{h}{4m\Delta v\pi } \\\ & \Delta x\ge \dfrac{6.6\times {{10}^{-34}}}{4\times 9.1\times {{10}^{-31}}\times 0.03\times 3.14} \\\ & \Delta x\ge 1.9248\times {{10}^{-3}}m \\\ \end{aligned}
Uncertainty in position = 1.92×103m1.92\times {{10}^{-3}}m

Therefore, option (C) 1.92×103m1.92\times {{10}^{-3}}m is correct.

Note: The uncertainty principle is a fundamental limitation of nature as this principle has no significance in our daily lives. Also, while calculating uncertainty for the substances which are invisible to our naked eyes, simultaneous calculations are not possible for velocity and position.