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Question

Chemistry Question on Thermodynamics

In an adiabatic expansion of a gas initial and final temperatures are T1 and T2 respectively then the change in internal energy of the gas is [R = gas constant, γ = adiabatic ratio]

A

R (T1 - T2)

B

R(T1T2)γ1\frac {R(T_1-T_2)}{γ-1}

C

R(T2T1)γ1\frac {R(T_2-T_1)}{γ-1}

D

zero

Answer

R(T1T2)γ1\frac {R(T_1-T_2)}{γ-1}

Explanation

Solution

The change in internal energy (ΔU) of a gas during an adiabatic expansion can be determined using the adiabatic equation:
ΔU =γγ1\frac {γ}{γ - 1} * R * (T2 - T1)
where γ is the adiabatic ratio or heat capacity ratio, R is the gas constant, T1 is the initial temperature, and T2 is the final temperature.
Therefore, the correct option is (B) R(T1T2)γ1\frac {R(T_1 - T_2)}{γ - 1}.