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Question

Chemistry Question on d block elements

In an acidified aqueous solution of Mn2+,Ni2+,Cu2+Mn ^{2+}, Ni ^{2+}, Cu ^{2+} and Hg2+Hg ^{2+} ions, H2SH _{2} S gas was passed. Precipitates are

A

MnS and CuS

B

NiS and HgS

C

MnS and NiS

D

CuS and HgS

Answer

CuS and HgS

Explanation

Solution

The black precipitate of CuSCuS and HgSHgS will be formed.
Cu2++H2SCuS( black )+H2Cu ^{2+}+ H _{2} S \rightarrow CuS (\text { black }) \downarrow+ H _{2} \uparrow
Hg2++H2SHgS( black )+H2Hg ^{2+}+ H _{2} S \rightarrow HgS (\text { black }) \downarrow+ H _{2} \uparrow