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Question

Chemistry Question on Redox reactions

In acidic medium, K2Cr2O7K_2Cr_2O_7 shows oxidizing action as represented in the half-reaction: Cr2O72+XH++Ye2A+ZH2OCr_2O_7^{2-} + XH^+ + Ye^- \rightarrow 2A + ZH_2O
XX, YY, ZZ, and AA are respectively:

A

8, 6, 4, and Cr2O3Cr_2O_3

B

14, 7, 6, and Cr3+Cr^{3+}

C

8, 4, 6, and Cr2O3Cr_2O_3

D

14, 6, 7, and Cr3+Cr^{3+}

Answer

14, 6, 7, and Cr3+Cr^{3+}

Explanation

Solution

The balanced reaction is:

Cr2O72+14H++6e2Cr3++7H2O\text{Cr}_2\text{O}_7^{2-} + 14\text{H}^+ + 6e^- \rightarrow 2\text{Cr}^{3+} + 7\text{H}_2\text{O}

From the reaction, we have:

X=14,Y=6,Z=7,A=Cr3+X = 14, \quad Y = 6, \quad Z = 7, \quad A = \text{Cr}^{3+}