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Question: In a reaction P + Q\(\rightarrow\) R + S, there is no change in entropy. Enthalpy change for the rea...

In a reaction P + Q\rightarrow R + S, there is no change in entropy. Enthalpy change for the reaction (ΔH\Delta H) is 12kJmol112kJmol^{- 1}Under what conditions, reaction will have negative value of free energy change?

A

If ΔH\Delta H is positive.

B

If ΔH\Delta H is negative.

C

If ΔH\Delta H is 24 kJmol1kJmol^{- 1}

D

If temperature of reaction is high.

Answer

If ΔH\Delta H is negative.

Explanation

Solution

: ΔG=ΔHTΔS,ΔS=0\Delta G = \Delta H - T\Delta S,\Delta S = 0 or TΔS=0ΔG=ΔHT\Delta S = 0\Delta G = \Delta H