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Question

Chemistry Question on Unit Cells

In a compound, atoms of element Y form ccp lattice and those of element X occupy 2/3rd2/3^{rd} of tetrahedral voids. The formula of the compound will be

A

X4Y3X_4Y_3

B

X2Y3X_2Y_3

C

X2YX_2Y

D

X3Y4X_3Y_4

Answer

X4Y3X_4Y_3

Explanation

Solution

From the given data, we have
Number of Y atoms in a unit cell = 4
Number of X atoms in a unit cell
=8×23=163= 8\times \frac{2}{3} = \frac{16}{3}
From the above we get the formula of the compound as X16/3Y4X_{16/3}Y_{4} or X4Y3X_{4}Y_{3}