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Question

Chemistry Question on Thermodynamics

In a closed insulated container a liquid is stirred with a paddle to increase the temperature which of the following is true : -

A

ΔE=W0,q=0\Delta E = W \neq 0 , q = 0

B

ΔE=W=q0\Delta E = W =q \neq 0

C

ΔE=0,W=q0\Delta E =0, W = q \neq 0

D

W=0ΔE=q0W = 0 \, \Delta E = q \neq 0

Answer

ΔE=W0,q=0\Delta E = W \neq 0 , q = 0

Explanation

Solution

In closed insulated container a liquid is stirred with a paddle to increase the temperature, therefore it behaves as adiabatic process, so, for it q=0q = 0. Hence, from first law of thermodynamics
ΔE=q+Wifq=0\Delta E=q+W\,\,i\,\,f\,\,q = 0
ΔE=W\therefore \Delta E=W but not equal to zero.