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Question

Chemistry Question on Unit Cells

In a close-packed body-centred cubic lattice of potassium, the correct relation between the atomic radius (r)(r) of potassium and the edge-length (a)(a) of the cube is

A

r=a2r=\frac{a}{\sqrt{2}}

B

r=a3r=\frac{a}{\sqrt{3}}

C

r=32ar=\frac{\sqrt{3}}{2} a

D

r=34ar=\frac{\sqrt{3}}{4} a

Answer

r=34ar=\frac{\sqrt{3}}{4} a

Explanation

Solution

\because For be packing, 3a=4r\sqrt{3} a=4 r r=34a\therefore r=\frac{\sqrt{3}}{4} \cdot a where a=a= edge length r=r= radius of lattice sphere