Question
Chemistry Question on Aldehydes, Ketones and Carboxylic Acids
In a Claisen condensation reaction (when an ester is treated with a strong base)
A
a proton is removed from the α -carbon to form a resonance stabilised carbanion of the ester
B
carbanion acts as a nucleophile in a nucleophilic acyl substitution reaction with another ester molecule
C
a new C?C bond is formed
D
All of the above statements are correct
Answer
All of the above statements are correct
Explanation
Solution
When two molecules of an ester undergo a condensation reaction, the reaction is called as Claisen condensation and product is a β - keto ester.
2CH3CH2C∣∣OOCH3\ce−>[(i)CH3O−][(ii)H+]
CH3CH2βC∣∣OC∣αH3CHC∣∣OOCH3+CH3OH
Mechanism
Step I
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Step II
Step III