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Question

Chemistry Question on Solutions

In a 0.2 molal aqueous solution of a weak acid HX the degree of ionization is 0.3. Taking KfK_f for water as 1.85, the freezing point of the solution will be nearest to

A

-0.480^\circC

B

-0.360^\circC

C

-0.260^\circC

D

#ERROR!

Answer

-0.480^\circC

Explanation

Solution

HX<=>H++X { HX <=> H^+ + X^-} i=10.3+0.3+0.31=1.3i = \frac{1 - 0.3 + 0.3 + 0.3 }{1} = 1.3 ΔTf=iKfm\Delta T_f = i \, K_f \, m = 1.3×1.85×0.2 1.3 \times 1.85 \times 0.2 = 0.48 \therefore TfT_f = (0 - 0.48)^{\circ}C = 0-48^{\circ}C.