Question
Question: If \(\upsilon_{1}\) is the frequency of the series limit of Lyman series,\(\upsilon_{2}\) is the fre...
If υ1 is the frequency of the series limit of Lyman series,υ2 is the frequency of the first line of Lyman series and υ3 is the frequency of the series limit of the Balmer sereis, then
A
υ1−υ2=υ3
B
υ1=υ2−υ3
C
υ21=υ11+υ31
D
υ11=υ21+υ31
Answer
υ1−υ2=υ3
Explanation
Solution
For Lyman series
υ=R[121−n21]
Where n = 2, 3, 4……….
For the series limit of Lyman series n=∞
υ1=Rc[121−∞21]=Rc …… (i)
For the first line of Lyman series n = 2
υ2=Rc[121−221]=43Rc …… (ii)
For Balmer series
υ=R[121−n21]
Where n = 3, 4, 5……….
For the series limit of Balmer series n=∞
υ3=Rc[221−∞21]=4Rc …… (iii)
From equation (i), (ii) and (iii) we get
υ1=υ2+υ3 or υ1−υ2=υ3