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Question

Chemistry Question on Thermodynamics

If three moles of an ideal gas at 300 K expand isothermally from 30 dm3 to 45 dm3 against a constant opposing pressure of 80 kPa, then the amount of heat transferred is ______ J.

Answer

Using the first law of thermodynamics:

ΔU=Q+W\Delta U = Q + W

For an isothermal process, ΔU=0\Delta U = 0, so Q=WQ = -W.

W=PextΔV=80×103×(4530)×103=1200JW = -P_{\text{ext}} \Delta V = -80 \times 10^3 \times (45 - 30) \times 10^{-3} = -1200 \, \text{J}