Question
Question: If the uncertainty in the position is equal to the wavelength of an electron , how certain can we be...
If the uncertainty in the position is equal to the wavelength of an electron , how certain can we be about the velocity. Determine an expression for Δvxvx.
Solution
Heisenberg’s uncertainty principle is used to tackle this problem and in deriving the expression. De Broglie waves are applicable in the case of electrons and not photons because photons have no mass.
Complete step by step answer:
The Heisenberg uncertainty principle tells us that the product of uncertainty in position and uncertainty in momentum is greater than or equal to 2πh. That is,
ΔxΔp⩾2πh −−−−− (1)
Where h is the planck's constant.
The de Broglie wavelength is given by,
λ=ph ⇒λ=mvxh
When Δx=λ , (1) becomes
mvxh×Δpx⩾2πh −−−−− (2)
Since p=mv ⇒Δp=mΔv
(2) becomes, mvx1×mΔvx⩾2π1
Cancelling the common factors in numerator and denominator, we get,
⇒vx1×Δvx⩾2π1
⇒ vxΔvx⩾2π1
Taking the reciprocal on both sides,
Δvxvx⩽2π
The wavelength for an electron is of the order 10−9 , therefore uncertainty in the velocity is large for maintaining the inequality ΔxΔp⩾2πh.
Therefore, This is true because Δvx should be very large in order to make Δvxvx⩽2π.
Note: The uncertainty principle states that if we know the exact position of a particle then we have no information of its momentum and vice versa. The more we know about either of these values, the less we know about the other. In other words, A particle is dispersed over space, so it does not occupy a single definite location, but rather a range of positions. Similarly, because a particle is made up of a packet of waves, each of which has its own momentum, the momentum of a particle can only be described as a range of momentum at best.