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Chemistry Question on Buffer Solutions

If the pKapKa of lactic acid is 55 , then the pHpH of 0.005M0.005 \,M calcium lactate solution at 25C25^{\circ} C is ______ ×101\times 10^{-1} (Nearest integer) Lactic acid
Strcuture

Answer

The correct answer is 85.
Concentration of calcium lactate =0.005M,: concentration of lactate ion =(2×0.005)M. Calcium lactate is a salt of weak acid + strong base ∴ Salt hydrolysis will take place.
pH=7+21​(pKa+logC)
=7+21​(5+log(2×0.005))
=7+21​[5−2log10]=7+21​×3=8.5=85×10−1