Question
Chemistry Question on Atomic Models
If the photon of the wavelength 150 pm strikes an atom and one of its inner bound electrons is ejected out with a velocity of 1.5 × 107 ms–1, calculate the energy with which it is bound to the nucleus.
The energy of the incident photon (E) is given by,
E =λhc
= (150×10−12m)(6.626×10−34Js)(3.0×108ms−1)
= 1.3252 × 10-15 J
≈ 1.3252 × 10-16 J
The energy of the electron ejected (K.E) = 21mev2 = 21 (9.10939 × 10-31kg)(1.5 × 107 ms-1)2
= 10.2480 × 1017 J = 1.025 × 1016 J
Hence, the energy with which the electron is bound to the nucleus can be obtained as E = K.E
= 13.252 × 10 -16J -1.025 × 1016 J
= 12.227 × 1016 J
= 1.602×10−1912.227×10−16 eV = 7.6 × 103 eV
4λ0−20005λ0−2000 = (2.555.35)2 = 6.502528.6225
4λ0−20005λ0−2000 = 4.40177
17.6070λ0 - 5λ0 = 8803.537 - 2000
λ0 = 12.6076805.537
λ0 = 539.8 nm
λ0 ≈ 540 nm