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Question

Chemistry Question on Thermodynamics terms

If the melting point of ice is 0?C0^?C and latent heat of fusion is 5.46kJmol15.46\, kJ\, mol^{-1}, the entropy change for the conversion of 18g18\, g of ice to water at one atmosphere is

A

5.46Jmol1K15.46\, J \,mol^{-1}\, K^{-1}

B

20Jmol1K120\, J \,mol^{-1}\, K^{-1}

C

50Jmol1K150\, J \,mol^{-1}\, K^{-1}

D

360Jmol1K1360\, J \,mol^{-1}\, K^{-1}

Answer

20Jmol1K120\, J \,mol^{-1}\, K^{-1}

Explanation

Solution

ΔSf=ΔHfTm.p.\Delta S_{f} =\frac{\Delta H_{f}}{T_{m.p.}} =5.46×1000273=\frac{5.46\times1000}{273} =20Jmol1K1=20\, J \,mol^{-1}\,K^{-1}