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Question: If the lattice parameter of \( Si \) is \( 5.43A^\circ \) and the mass of atom \( Si \) is \( 28.08 ...

If the lattice parameter of SiSi is 5.43A5.43A^\circ and the mass of atom SiSi is 28.08×1.66×1027kg28.08 \times 1.66 \times {10^{ - 27}}kg , the density of silicon in kgm3kg{m^{ - 3}} is:
[Given: Silicon has a diamond cubic structure.]
(a) 23302330
(b) 11151115
(c) 34453445
(d) 16731673

Explanation

Solution

The silicon is a chemical compound having symbol SiSi and atomic number 1414 . The silicon is a tetravalent, metalloid and semiconductor (Pure Silicon is needed for these purposes) in computers and microelectronics.
Density of the atom,
d=mVd = \dfrac{m}{V}
Where, dd is the density, VV is the volume and mm is the mass of the compound.
Volume of the cube,
V=l3V = {l^3}
Where, ll is the side of the cube.

Complete step-by-step answer:
First of all, we are writing the data given in the question.
Given data:
Mass of atom =28.08×1.66×1027= 28.08 \times 1.66 \times {10^{ - 27}}
Lattice parameter of the atom =5.43A=5.43×1010= 5.43A^\circ = 5.43 \times {10^{ - 10}}
Lattice parameter of the atom is the measure of the side of the cube.
Now, putting the value of side as the lattice parameter of the atom and finding the volume of the cube-
So, the volume of the atom is 1.6×1028m31.6 \times {10^{ - 28}}{m^3} .
Now, we have to find the mass of the unit cell.
As in the question given that the Silicon atom is having a cubic structure. The number of atoms in the unit cells in the cubic structure is eight.
m=8×mass  of  one  atom=8×28.08×1.66×1027kg=3.73×1025kgm = 8 \times mass\;of\;one\;atom = 8 \times 28.08 \times 1.66 \times {10^{ - 27}}kg = 3.73 \times {10^{ - 25}}kg
So, the calculated mass of the unit cell is 3.73×1025kg3.73 \times {10^{ - 25}}kg .
Now, putting the value of mass and volume in the density formula as given in the question.
d=mV=3.73×10251.6×1028=2330kgm3d = \dfrac{m}{V} = \dfrac{{3.73 \times {{10}^{ - 25}}}}{{1.6 \times {{10}^{ - 28}}}} = 2330kg{m^{ - 3}}
So, the density of the atom will be 2330kgm32330kg{m^{ - 3}} .
Hence, the correct option is (a) 23302330 .

Additional Information:
Density is mass per unit volume. It is an intensive property (The intensive property is the property of matter that does not change with the amount of matter).

Note:
The cubic crystal system is the system in which the shape of the unit cells are cubic in structure and the unit cells are the smallest repeating unit having the total symmetry of the crystal structure.