Question
Question: If the equivalence point is at a pH of 8.4 in acid-base titration, then ---------- indicator should ...
If the equivalence point is at a pH of 8.4 in acid-base titration, then ---------- indicator should be used.
A. methyl violet
B. alizarin yellow
C. phenolphthalein
D. methyl red
Solution
Titration is the process of chemical analysis in which the quantity of some constituent of a sample is determined by adding to the measured sample an exactly known quantity of another substance with which the desired constituent reacts in a definite, known proportion. Titrations are mainly classified into 4 types such as acid-base, redox, precipitation and complexometric titrations. Here the question deals with acid-base titrations.
Complete step by step answer:
Here, we have given that in acid base titration the equivalence point is at a pH of 8.4.For each specific pH range we have to use specific indicators. Follow the table given below
Indicator.
Indicator | Color on acidic side | Color on basic side | Range of pH |
---|---|---|---|
Methyl violet | Yellow | Violet | 0.0-1.6 |
Bromophenol blue | Yellow | Blue | 3.0-4.6 |
Methyl orange | Red | Yellow | 3.1-4.4 |
Methyl red | Red | Yellow | 4.4-6.3 |
Litmus | Red | Blue | 5.0-8.0 |
Bromothymol blue | Yellow | Blue | 6.0-7.6 |
Phenolphthalein | Colorless | Pink | 8.3-10.0 |
Alizarin yellow | Yellow | Red | 10.1-12.0 |
In the given that the equivalence pH is at 8.4.By analyzing that table we get that Phenolphthalein is used for this acid-base titration.
Hence, the correct option is C.
Note:
Acid–base titrations depend on the neutralization between an acid and a base when mixed in solution. In addition to the sample, an appropriate pH indicator is added to the titration chamber, representing the pH range of the equivalence point. The acid–base indicator indicates the endpoint of the titration by changing color. The endpoint and the equivalence point are not exactly the same because the equivalence point is determined by the stoichiometry of the reaction while the endpoint is just the color change from the indicator. Thus, a careful selection of the indicator will reduce the indicator error.