Question
Chemistry Question on Atomic Models
If the electron's position is measured within an accuracy of + 0.002 nm, calculate the uncertainty in the electron's momentum. Suppose the momentum of the electron is 4πmh × 0.05 nm, is there any problem in defining this value?
From Heisenberg's uncertainty principle,
Δx × Δp =4πh ⇒ Δp = Δx1 . 4πh
Where, Δx = uncertainty in the position of the electron
Δp = uncertainty in momentum of the electron
Substituting the values in the expression of Δp:
Δp = 0.0021nm × 4×(3.14)6.626×10−34Js
= 2.637 × 10-23 Js-1
Δp = 2.637 × 1023 kgms (1 J = 1 kgms 2s)
∴ Uncertainty in the momentum of the electron = 2.637 × 1023 kgms-1.
Actual momentum = 4πmh× 0.05 nm
=4×3.14×5.0×10−11m6.626×10−34Js
= 1.055 × 10-24 kgms-1
Since the magnitude of the actual momentum is smaller than the uncertainty, the value cannot be defined .