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Question: If minimum possible work is done by a refrigerator in converting 100 grams of water at 0°C to ice, h...

If minimum possible work is done by a refrigerator in converting 100 grams of water at 0°C to ice, how much heat (in calories) is released to the surroundings at temperature 27°C (Latent heat of ice = 80 Cal/gram) to the nearest integer ?

Answer

8791

Explanation

Solution

  1. Calculate the heat absorbed from the cold reservoir (QCQ_C) as the latent heat of fusion: QC=mass×latent heat of fusion=100g×80Cal/g=8000CalQ_C = \text{mass} \times \text{latent heat of fusion} = 100 \, \text{g} \times 80 \, \text{Cal/g} = 8000 \, \text{Cal}.
  2. Convert temperatures to Kelvin: TC=0C=273KT_C = 0^\circ C = 273 \, K and TH=27C=300KT_H = 27^\circ C = 300 \, K.
  3. For minimum work (ideal Carnot refrigerator), the heat released to the hot reservoir (QHQ_H) is given by: QH=QC×THTCQ_H = Q_C \times \frac{T_H}{T_C}
  4. Substitute values and calculate: QH=8000Cal×300K273K=8000×10091Cal8791.2CalQ_H = 8000 \, \text{Cal} \times \frac{300 \, K}{273 \, K} = 8000 \times \frac{100}{91} \, \text{Cal} \approx 8791.2 \, \text{Cal}.
  5. Rounding to the nearest integer gives 8791 Cal.