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Question: If equivalent conductance of \(\rightarrow\) benzoic acid is \(\rightarrow\) and if the conductance ...

If equivalent conductance of \rightarrow benzoic acid is \rightarrow and if the conductance of benzoate ion and \rightarrow ion are 42 and \rightarrow respectively. its degree of dissociation is.

A

39%

B

3.9%

C

0.35%

D

0.039%

Answer

3.9%

Explanation

Solution

Λm(C6H5COOH)o=Λ(C6H5COO)o+Λ(H+)o\Lambda_{m(C_{6}H_{5}COOH)}^{o} = \Lambda_{(C_{6}H_{5}COO^{-})}^{o} + \Lambda_{(H^{+})}^{o}

=42+288.42=330.42α=ΛmcΛmo=12.8330.42=3.9%= 42 + 288.42 = 330.42\alpha = \frac{\Lambda_{m}^{c}}{\Lambda_{m}^{o}} = \frac{12.8}{330.42} = 3.9\%