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Question

Chemistry Question on d -and f -Block Elements

If Cu2+Cu^{2+} ions is treated with excess of KCNKCN, the complex formed is

A

K2[Cu(CN)4]K_2[Cu (CN)_4]

B

K3[Cu(CN)4]K_3[Cu(CN)_4]

C

K4[Cu(CN)6]K_4[Cu (CN)_6]

D

All of these

Answer

K3[Cu(CN)4]K_3[Cu(CN)_4]

Explanation

Solution

Cu2+Cu^{2+} is reduced to Cu+Cu^{+} which forms complex K3[Cu(CN)4]K_{3}[Cu(CN)_{4}] 2CuSO4+10KCN2K3[Cu(CN)4]+2K2SO4+(CN)22CuSO_{4}+10KCN \to 2K_{3}[Cu(CN)_{4}] + 2K_{2}SO_{4}+(CN)_{2}