Question
Question: If \(C_{s}\) be the velocity of sound in air and \(C\) be the rms velocity, then \[\begin{aligned}...
If Cs be the velocity of sound in air and C be the rms velocity, then
& A.{{c}_{s}}>c \\\ & B.{{c}_{s}}=c \\\ & C.{{c}_{s}}=c{{\left\\{ \dfrac{\gamma }{3} \right\\}}^{\dfrac{1}{2}}} \\\ & D.\text{no relation} \\\ \end{aligned}$$Solution
Root-mean-square velocity of gases is the root of the mean of the squares of velocity of all the gas particles in the system, this is taken into calculation , because of the random motion and velocities of the gas particles. And we also know from the ideal gases that the speed of the sound in air is given as v=MγRT, to find the necessary equation, we need to compare the two equations.
Formula used:
vrms=Mm3RT and v=MγRT
Complete step by step solution:
The mean speed, most probable speed and root-mean-square speed are properties of the Maxwell- Boltzmann distribution, which studies the molecular collision of the gas molecules, on the basis of statistical thermodynamics. Maxwell–Boltzmann statistics gives the average number of particles found in a given single-particle microstate.It is assumed that the particles don’t interact, and exist as independent particles.
The rms is given as vrms=Mm3RT, where R is the gas constant, T is the absolute temperature and Mm is the molar mass of the gas particles.
Here, we have C=Mm3RT
Similarly, the velocity of the sound in air, assuming air as ideal gas, is given as v=MγRT, where γ is the adiabatic index, more commonly known as the degree of freedom, R is the universal gas constant, T is the absolute temperature of the gas and M is the molar mass of the gas.
Here, we have Cs=MγRT
Taking the ratio between the speeds, we get CCS=Mm3RTMγRT
⟹CCS=3γ
∴CS=C(3γ)21
Hence the correct answer is option C.{{c}_{s}}=c{{\left\\{ \dfrac{\gamma }{3} \right\\}}^{\dfrac{1}{2}}}
Note:
Rms velocity is taken instead of normal velocity because of the random motion and velocities of the gas particles. From the equation it is clear that vrms∝T, vrms∝M1. Here , it is assumed that the particles don’t interact, and exist as independent particles.