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Question: If at 200 K & 500 atm, density of $CH_4$ is 0.25 gm/ml then its compressibility factor (Z) is...

If at 200 K & 500 atm, density of CH4CH_4 is 0.25 gm/ml then its compressibility factor (Z) is

A

1

B

2

C

0.5

D

0.25

Answer

2

Explanation

Solution

The compressibility factor (Z) is calculated using the formula Z=PMρRTZ = \frac{PM}{\rho RT}. First, convert the density from g/ml to g/L: 0.25 g/ml=250 g/L0.25 \text{ g/ml} = 250 \text{ g/L}. The molar mass of CH4CH_4 is 16 g/mol. Substitute the given values: P = 500 atm, M = 16 g/mol, ρ\rho = 250 g/L, R = 0.08 L-atm/K-mol, and T = 200 K. Z=(500 atm)×(16 g/mol)(250 g/L)×(0.08 L-atm/K-mol)×(200 K)=80004000=2Z = \frac{(500 \text{ atm}) \times (16 \text{ g/mol})}{(250 \text{ g/L}) \times (0.08 \text{ L-atm/K-mol}) \times (200 \text{ K})} = \frac{8000}{4000} = 2.