Question
Chemistry Question on Unit Cells
If �a� stands for the edge length of the cubic systems : simple cubic, body centred cubic and face centred cubic, then the ratio of radii of the spheres in these systems will be respectively,
A
21a:43a:221a
B
21a:3a:21a
C
21a:23a:23a
D
1a:3a:2a
Answer
21a:43a:221a
Explanation
Solution
Following generalization can be easily derived for various types of lattice arrangements in cubic cells between the edge length (a) of the cell and r the radius of the sphere.
For simple cubic:a=2rorr=2a
For body centred cubic :a=22rorr=221a
Thus the ratio of radii of spheres for these will be
simple: bcc: fcc
=2a:43a:221ai.e.
option (a) is correct answer.