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Question

Chemistry Question on Order of reaction

If 75%\% of a first-order reaction gets completed in 32 minutes, the time taken for 50%\% completion of this reaction is:

A

16 minutes

B

78 minutes

C

8 minutes

D

4 minutes

Answer

8 minutes

Explanation

Solution

For a first-order reaction, the relationship between time and completion is given by: t=0.693k For 75% completion, the time is related to k as follows: t75%=t50%0.693×11 Given that the 75% completion time is 32 minutes, the time for 50% completion is: t50%=320.6938minutes\text{For a first-order reaction, the relationship between time and completion is given by:} \\\ t = \frac{0.693}{k} \\\ \text{For 75\% completion, the time is related to } k \text{ as follows:} \\\ t_{75\%} = \frac{t_{50\%}}{0.693 \times 11} \\\ \text{Given that the 75\% completion time is 32 minutes, the time for 50\% completion is:} \\\ t_{50\%} = \frac{32}{0.693} \approx 8 \, \text{minutes}