Question
Chemistry Question on Chemical Kinetics
If 25% of a radioactive element is left after 40 days, then its half life period is
A
80 days
B
20 days
C
4 days
D
10 days.
Answer
20 days
Explanation
Solution
Radioactive disintegration follows the first order kinetics.
Disintegration constant (k)=t2.303logNN0
k=122.303log25100
k=122.303log(2)2=402×2.303log2
k=402×2.303×0.3010=0.035days−1
Now, k=t1/22.303log50100
0.035=t1/22.303log2
t1/2=0.0352.303×0.3010=19.80days≈20days
So, the correct option is (B): 20 days.