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Question: If \( 0.5 \) moles of \( BaC{l_2} \) is mixed with \( 0.20 \) moles of \( N{a_3}P{O_4} \) , the maxi...

If 0.50.5 moles of BaCl2BaC{l_2} is mixed with 0.200.20 moles of Na3PO4N{a_3}P{O_4} , the maximum number of moles of Ba3(PO4)2B{a_3}{(P{O_4})_2} that can be formed is:
(A) 0.10.1
(B) 0.20.2
(C) 0.50.5
(D) 0.70.7

Explanation

Solution

Hint : We will write what is given in the question. We will write the equation and in the balanced form. Then the coefficients will tell the ratio of reactant and products. Then we will calculate the yield of Ba3(PO4)2B{a_3}{(P{O_4})_2} after the reaction is completed. Let us write the step by step solution now.

Complete Step By Step Answer:
Step1. Moles of BaCl2BaC{l_2} given is 0.50.5 moles.
Moles of given is Na3PO4N{a_3}P{O_4} 0.200.20 moles.
The new product that will be formed is Ba3(PO4)2B{a_3}{(P{O_4})_2} .
Step2. The reaction will happen between Barium Chloride and Sodium Phosphate. The reaction will be a double substitution reaction. The reaction is given below.
3BaCl2+2NaPO4Ba3(PO4)2+6NaCl3BaC{l_2} + 2NaP{O_4} \to B{a_3}{(P{O_4})_2} + 6NaCl
Step3. The coefficients of the balanced equation will give us the idea about the ratio of the reactants and the products that are formed. By seeing the reaction, we see that three moles of the BaCl2BaC{l_2} will react with two moles of Na3PO4N{a_3}P{O_4} and produce one mole of the Ba3(PO4)2B{a_3}{(P{O_4})_2} .
Step4. The ratio of the BaCl2BaC{l_2} : Na3PO4N{a_3}P{O_4} will be 3:23:2
0.50.5 mole of BaCl2BaC{l_2} needs 23×0.5=0.333\frac{2}{3} \times 0.5 = 0.333 of Na3PO4N{a_3}P{O_4} . So it is the limiting agent and BaCl2BaC{l_2} is in excess amount.
So the 0.200.20 moles of Na3PO4N{a_3}P{O_4} will create 0.10.1 of the Ba3(PO4)2B{a_3}{(P{O_4})_2} . Because two mole of the Na3PO4N{a_3}P{O_4} create the one mole of the Ba3(PO4)2B{a_3}{(P{O_4})_2} .
Hence Option A is the correct option.

Note :
A double substitution reaction exchanges the cations or the anions of the two ionic compounds. It is also known as precipitation reaction sometimes when the product is solid precipitate. Often the solubility rules are used to predict if the double replacement reactions will occur or not.