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Chemistry Question on Some basic concepts of chemistry

If 0.5 mol of BaCl2BaCl_2 is mixed with 0.2 mol of Na3PO4Na_3PO_4 the maximum number of moles of Ba3(PO4)2Ba_3(PO_4 )_2 that can be formed is

A

0.7

B

0.5

C

0.1

D

0.2

Answer

0.1

Explanation

Solution

The balanced chemical reaction is
3BaCl2+2Na3PO4Ba3(PO4)2+6NaCl3BaCl_2 + 2Na_3PO_4 \rightarrow \, Ba_3(PO_4)_2 + 6NaCl
In this reaction, 3 moles ofBaCl2 BaCl_2 combines with 2 moles of Na3PO4Na_3PO_4
. Hence, 0.5 mole of of BaCl2BaCl_2 require
=23×0.5=0.33moleofNa3PO4\, \, \, \, \, \, \, \, \, = \frac{2}{3} \times 0.5 = 0.33 \, mole \, of \, Na_3PO_4
Since, available Na3PO4Na_3PO_4 (0.2 mole) is less than required mole (0.33),
it is the limiting reactant and would determine the amount of product Ba3(PO4)2Ba_3(PO_4)_2
2molesofNa3PO4gives1moleBa3(PO4)2\because \, \, \, \, 2 moles \, of \, Na_3PO_4 \, gives \, 1 \, mole \, Ba_3(PO_4)_2 .2 moles of Na3PO4Na_3PO_4 gives 1 mole Ba3(PO4)2Ba_3(PO_4)_2
\therefore \, \, 0.2 mole of Na3PO4Na_3PO_4 would give 12×0.2 \frac{1}{2} \times 0.2
=0.1moleBa3(PO4)2\, \, \, \, \, \, \, \, \, \, = 0.1 \, mole \, Ba_3 (PO_4)_2