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Question

Chemistry Question on Organic Chemistry- Some Basic Principles and Techniques

Identify the products A and B in the reactions: RX+AgCNA+AgXR-X + AgCN \longrightarrow A + AgX RX+KCNB+KXR-X + KCN \longrightarrow B+ KX

A

A = RNC; B = RCN

B

A = R - CN; B = RCN

C

A - RNC; B = RNC

D

A = RCN; B = RNC

Answer

A = RNC; B = RCN

Explanation

Solution

The products A and B in the reactions can be identified as follows:
R-X+AgCNA+AgX\text{R-X} + \text{AgCN} \rightarrow \text{A} + \text{AgX}
In this reaction, the cyanide ion (CN\text{CN}^-) acts as a nucleophile and substitutes the leaving group X in RXR-X.
The resulting product A is formed by the attachment of the cyano group(CN)(-CN) to the R group, while the silver ion (Ag+) combines with the leaving group X to form AgX.
R-X+KCNB+KX\text{R-X} + \text{KCN} \rightarrow \text{B} + \text{KX}
In this reaction, the cyanide ion CN\text{CN}^- from KCN also acts as a nucleophile and substitutes the leaving group X in R-X. The resulting product B is formed by the attachment of the cyano group (-CN) to the R group, while the potassium ion (K+) combines with the leaving group X to form KX.
Based on the above reactions, we can conclude that:
A=RCNA = RCN (cyano group attached to R)
B=RCNB = R - CN (cyano group attached to R)
Therefore, the correct identification of products A and B in the reactions is (A) A=RNC;B=RCNA = \text{RNC}; \quad B = \text{RCN}