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Question

Chemistry Question on Aldehydes, Ketones and Carboxylic Acids

Identify the product (P) in the following reaction:product

A

1br

B

2br

C

D

4br

Answer

1br

Explanation

Solution

The given reaction is an example of the Hell-Volhard-Zelinsky (HVZ) reaction, which selectively brominates the α\alpha-carbon of carboxylic acids in the presence of Br2_2 and red phosphorus. The reaction mechanism involves the formation of an α\alpha-brominated carboxylic acid.
COOHBr2/Red PCOOH-BrH2OCOOH-Br (Product)\text{COOH} \xrightarrow{\text{Br}_2/\text{Red P}} \text{COOH-Br} \xrightarrow{\text{H}_2\text{O}} \text{COOH-Br (Product)}
Thus, the product formed is the α\alpha-bromo derivative of the given carboxylic acid.